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Methylenediphenyl Diisocyanate CAS#101-68-8

Methylenediphenyl Diisocyanate CAS#101-68-8

Basic Information

Methylenediphenyl Diisocyanate
MDI

Methylene diphenyl diisocyanate, commonly abbreviated MDI, is an aromatic isocyanate used to make polyurethane materials through reaction with polyols. Suitable grades are employed in elastomers, adhesives, sealants and composite binders. Polymeric forms are associated with rigid insulation foams and panels. Monomeric, polymeric and modified materials differ in composition and processing behavior, so these forms should not be treated as interchangeable.

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product description

MDI for Polyurethane Production: Methylene diphenyl diisocyanate (MDI) is an aromatic isocyanate that reacts with polyols to produce polyurethane materials. Monomeric, polymeric, and modified MDI grades differ in composition, functionality, viscosity, and processing requirements.


Rigid Foams and PU Panels: Polymeric MDI is widely used in rigid polyurethane foams for insulation panels, sandwich panels, refrigeration equipment, and building insulation. Performance depends on the formulation, processing conditions, and selected grade.


Elastomers and Adhesives: Suitable MDI grades are used in polyurethane elastomers, adhesives, sealants, and binders. Grade selection influences flexibility, hardness, bonding strength, and curing behavior.


Composite Materials: MDI-based systems are used in wood-based panel binders and polyurethane composites, supporting bonding and structural performance in appropriately designed formulations.


Grade Selection: Please specify the MDI type, isocyanate content (NCO%), viscosity, functionality, intended application, and processing conditions. Appearance and storage temperature requirements vary by grade and should follow the product’s technical data sheet.


Handling and Storage: MDI is harmful if inhaled, irritates the respiratory tract, and may cause respiratory or skin sensitization. Use suitable ventilation and protective equipment according to the SDS. Contact with water releases carbon dioxide and heat, potentially causing pressure buildup in closed containers. Keep containers tightly closed, dry, and protected from moisture, and follow grade-specific storage instructions.

Products Description of Methylenediphenyl Diisocyanate CAS#101-68-8

4,4'-Diphenylmethane diisocyanate (MDI) and its derivatives are essential chemical industry materials. They are used in polyurethane production, as raw materials/intermediates for high-performance polymers, in functional material development, and in analytical research and chemical formulation additives.

Product Specifications

Parameters


Melting point38-44 °C
Boiling point392 °C
density1.19
vapor pressure0.066 hPa (20 °C)
refractive index1.5906 (estimate)
Fp196 °C
storage temp.-20°C
solubility2g/l (decomposition)
formsolid
colorWhite to Almost white
Specific Gravity1.18
explose limit0.4%(V)
Water Solubilitydecomposes
FreezingPoint37℃
SensitiveMoisture Sensitive/Lachrymatory
BRN797662
Exposure limitsTLV-TWA 0.051 mg/m3 (0.005 ppm) (ACGIH and NIOSH); ceiling (air) 0.204 mg/m3 (0.02 ppm)/10 min (NIOSH and OSHA); IDLH 102 mg/m3 (10 ppm).
Dielectric constant10.0(Ambient)
Stability:Stable. Combustible. Incompatible with strong oxidizing agents. Reacts violently with alcohols.
CAS DataBase Reference101-68-8(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1,1'-methylenebis[4-isocyanato-(101-68-8)
IARC3 (Vol. 19, Sup 7, 71) 1999
EPA Substance Registry System4,4'-Methylenedi(phenyl isocyanate) (101-68-8)


Safety Information


Hazard CodesXn,T,C
Risk Statements42/43-36/37/38-20-48/20-40
Safety Statements45-36/37-23
RIDADR2206
OEBD
OELTWA: 0.05 mg/m3 (0.005 ppm), Ceiling: 0.2 mg/m3 (0.020 ppm) [10-minute]
WGK Germany1
RTECSNQ9350000
Autoignition Temperature>600 °C
Hazard NoteToxic/Corrosive/Lachrymatory/Moisture Sensitive
TSCAYes
HazardClass6.1
PackingGroupII
HS Code29291090
Hazardous Substances Data101-68-8(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 9000 mg/kg
IDLA75 mg/m3


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Shipping And Transportation

Delivery Time

Inventory 2-3 working days New manufacturing 7-10 working days

Mode of Transportation
1. By Air, fast but expensive.
2. By Sea, usual and economy.
3. By Train, suit for middle Asia countries.
4. By Express, suit for small package.
We only provide highest quality goods available, accompanied by after support!

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1. What products does Shandong Junzheng Chemical supply?
We supply inorganic chemicals, organic solvents, water treatment chemicals, and surfactants, including calcium chloride, soda ash, sodium bicarbonate, caustic soda, citric acid, ethyl acetate, and SLES. Please contact us to confirm specific product availability.


2. Which industries do your products serve?
Our products serve pharmaceutical, agrochemical, dye, rubber, construction, coal processing, and other chemical industries. Product suitability depends on the required grade, specifications, and application.


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Please provide the product name, CAS number, required specifications, quantity, packaging requirements, and destination port. These details help us prepare an accurate quotation.


4. How do you control product quality?
We follow strict quality testing procedures supported by technical personnel, research equipment, and an established management system. Specific quality requirements can be confirmed before placing an order.


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